Infrared spectroscopic properties of goethite: anharmonic broadening,long-range electrostatic effects and Al substitution     

Marc Blanchard  Etienne Balan  Paola Giura  Keevin Béneut  Haohao Yi  Guillaume Morin  Carlos Pinilla  Michele Lazzeri  Andrea Floris 《Physics and Chemistry of Minerals》2014,41(4):289-302

The infrared spectrum and its temperature dependence (20–320 K) were collected on a synthetic goethite sample (α-FeOOH). In addition, the infrared powder absorption spectrum of goethite and aluminum-substituted goethite was computed using ab initio quantum mechanical calculations based on density functional theory. This combined experimental and theoretical approach allows (1) the unequivocal assignment of absorption bands to the corresponding vibrational modes, (2) separate identification of the effects of the particle shape and of the aluminum substitution on the infrared spectrum, and (3) a discussion of the anharmonic properties and the origin of the line broadening in goethite. In particular, the two well-resolved OH bending absorption bands show different temperature evolution. Their detailed analysis suggests that the broadening of the band at ~800 cm^?1 cannot be described solely by a usual three-phonon process. The strong anharmonic behavior of this mode implies the addition of a four-phonon process, such as a pure dephasing process. In our calculations, the effect of the Hubbard U correction is also investigated and found to be most visible on the OH stretching and bending modes, in relation to the associated structural relaxation. The OH stretching frequencies decrease, leading to a better agreement with experimental frequencies, while the OH bending frequencies increase.  相似文献   

New constraints on modified Newtonian dynamics from galaxy clusters     

Etienne Pointecouteau  Joseph Silk 《Monthly notices of the Royal Astronomical Society》2005,364(2):654-658

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A flash flood hazard assessment in dry valleys (northern France) by cellular automata modelling     

Johnny Douvinet  Marco J. Van De Wiel  Daniel Delahaye  Etienne Cossart 《Natural Hazards》2015,75(3):2905-2929

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Liquidus surfaces of ultracalcic primitive melts: formation conditions and sources   总被引：4，自引：1，他引：3  

Etienne?MédardEmail author  Max?W.?Schmidt  Pierre?Schiano 《Contributions to Mineralogy and Petrology》2004,148(2):201-215

CaO-rich, Al₂O₃-poor ultracalcic primitive melts occur at mid-ocean-ridges, back-arc basins, ocean islands and volcanic arcs. They are subdivided into a nepheline-normative alkaline-rich, silica-poor group uniquely found in arcs and in hypersthene-normative fairly refractory melts which occur in all of the above environments. The high CaO contents (to 19.0 wt%) and CaO/Al₂O₃ ratios (to 1.8) exclude an origin from fertile lherzolites at volatile-absent conditions. Experimental investigation of the liquidus of a hypersthene-normative and a nepheline-normative ultracalcic melt results in quite distinct pressure-temperature conditions of multiple saturation: whereas the hypersthene-normative liquid saturates in olivine + clinopyroxene at 1.2 GPa and 1,410°C, this occurs at 0.2 GPa and 1,220°C for the nepheline-normative ultracalcic liquid. Our results in combination with melting experiments from the literature suggest that hypersthene-normative melts result from melting of a refractory olivine + clinopyroxene ± orthopyroxene source at elevated mantle temperatures. Contrasting, nepheline-normative ultracalcic melts form from wehrlitic cumulates in the arc crust; to account for the high alkaline and low silica contents, and the relatively low temperatures, source wehrlites must have contained amphibole.  相似文献   

Petrology,U/Pb dating and (C-O) stable isotope constraints on the source and evolution of the adakite-related Mezcala Fe-Au skarn district,Guerrero, Mexico     

Gilles?LevresseEmail author  Eduardo?González-Partida  Alejandro?Carrillo-Chavez  Jordi?Tritlla  Antoni?Camprubí  Alain?Cheilletz  Dominique?Gasquet  Etienne?Deloule 《Mineralium Deposita》2004,39(3):301-312

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Zircon U–Pb geochronology of Ordovician magmatism in the polycyclic Ruitor Massif (Internal W Alps)     

François Guillot  Urs Schaltegger  Jean-Michel Bertrand  Étienne Deloule  Thierry Baudin 《International Journal of Earth Sciences》2006,95(1):1-1

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Corrigendum to “Revision of the Upper Cretaceous Rudists from Northwestern Peru” [South American Earth Science 17 (2004) 39–48]     

Jean Philip  Etienne Jaillard   《Journal of South American Earth Sciences》2005,19(4)

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Latest Precambrian to Early Cambrian U–Pb zircon ages of augen gneisses from Calabria (Italy), with inference to the Alboran microplate in the evolution of the peri-Gondwana terranes     

Francesca Micheletti  Pierre Barbey  Annamaria Fornelli  Giuseppe Piccarreta  Etienne Deloule 《International Journal of Earth Sciences》2007,96(5):843-860

In situ U–Pb dating of zircons from five samples of Calabrian augen gneisses shows that their protoliths are Latest Precambrian to Early Cambrian in age (562 ± 15, 547 ± 7, 540 ± 4, 539 ± 16 and 526 ± 10 Ma), and contain Archaean (3.1 Ga), Palaeoproterozoic (1.7–2.4 Ga) and Neoproterozoic (0.6–0.9 Ga) inheritance. Geochemical signature of augen gneisses is typical of high-K calc-alkaline post-collisional magmatism. Their Sr–Nd isotopic compositions [0.7093 < (⁸⁷Sr/⁸⁶Sr)_i < 0.7139; −3.2 < ɛ_Nd(t) < −5.4; 1.5 < T _DM < 1.7 Ga] indicate the involvement of a crustal component in significant proportions. The Calabrian augen gneisses have, therefore, to be distinguished from the orthogneisses of Sardinia and northern Algeria, and from the porphyroids of Sicily, which are Middle Ordovician. By contrast, the Calabrian augen gneisses show a close similarity to the Pan-African post-collisional granitoids of the northern edge of the West African craton (e.g. the Moroccan Anti-Atlas). This suggests a peri-Gondwana origin and corroborates previous palaeogeodynamic reconstructions attributing the Alboran microplate to the northern margin of the West African craton.  相似文献   

华北新太古代和中生代大陆下地壳中的水:以汉诺坝地区为例     

杨晓志  夏群科  樊祺诚  Etienne Deloule  郝艳涛 《地球化学》2007,36(2):113-119

应用显微傅里叶变换红外光谱技术,对华北克拉通北缘汉诺坝地区的太古宙地体麻粒岩和新生代玄武岩中捕虏体麻粒岩(中生代底侵成因)的主要组成矿物(单斜辉石、斜方辉石、斜长石和石榴子石)进行了详细分析.结果表明,无论是地体麻粒岩还是捕虏体麻粒岩,岩石中的主要组成矿物均含有结构水,主要以OH形式存在.同种产状麻粒岩的矿物水含量(H2O%)均存在较大的变化,而且都远远超出实验误差,表明下地壳内水的分布可能是不均一的.两种产状麻粒岩的矿物结构水含量有着显著的不同,地体麻粒岩中矿物的水含量是捕虏体麻粒岩的2倍以上.太古宙-古元古代形成的安徽女山新生代玄武岩中的捕虏体麻粒岩具有与汉诺坝太古宙地体麻粒岩相似的水含量范围,但明显高于汉诺坝中生代形成的捕虏体麻粒岩.由此看来,早期(太古宙-古元古代)下地壳的水含量要比中生代形成的下地壳高得多,这可能指示不同时代下地壳在形成机制和性质上的不同.  相似文献   

Behaviour of Li and its isotopes during metasomatism of French Massif Central lherzolites     

Christiane Wagner  Etienne Deloule 《Geochimica et cosmochimica acta》2007,71(17):4279-4296

Li behaviour and distribution in the mantle were investigated by ion microprobe in situ measurements on co-existing olivine (ol), orthopyroxene (opx), clinopyroxene (cpx) and amphibole (amp) in xenoliths from the French Massif Central. The fertile spinel lherzolites of this study record increasing degrees of mantle metasomatism, from unmetasomatised anhydrous samples through cryptically metasomatised samples to highly metasomatised amphibole-rich samples. In anhydrous lherzolites, Li is preferentially incorporated into olivine (1.1-1.4 ppm, average values) compared to pyroxenes (0.2-0.9 ppm). The hydrous samples clearly show enrichment of Li in ol (1.5-5.0 ppm), opx (1.1-2.4 ppm) and cpx (2.4-5.4 ppm), while amphibole incorporates less Li than the co-existing phases (0.8-1.3 ppm). Average δ⁷Li values range from +7.6 to +14.5‰ in ol, from 5.1 to +13.7‰ in opx and from 8.8 to +10.3‰ in cpx from the anhydrous lherzolites. A layered peridotite sample (Sdi) shows higher Li content in all phases, with lighter isotopic composition in opx and cpx (−0.6 and −2‰ average δ⁷Li values, respectively). In the hydrous lherzolites average δ⁷Li values both overlap and extend beyond these ranges in ol (up to 17.5 ‰) and in opx (up to 22.9‰), and vary widely in cpx (−2.7 to +9.7‰). Low δ⁷Li values are observed in some opx (−10.4‰) and cpx (−13‰) from sample Sdi, and in cpx from three hydrous samples (from −9.7 to −5.3‰). The different anhydrous phases from the hydrous samples show large intra-grain variations in Li isotopic ratios (e.g., up to 18‰) compared to the same phases from the anhydrous samples (mostly less than 6‰), excepting sample Sdi which has up to 20.4‰ variation in cpx. Similar to the anhydrous silicates, amphiboles show a wide variation of δ⁷Li values on the intra-grain scale (2-27‰). These variations are interpreted to result from fractionation processes during metasomatism by a silicate melt undergoing compositional changes as it percolates through and reacts with the peridotite phases. Thus Li abundances and isotopic in situ measurements are useful for tracing metasomatic processes but the heterogeneities observed in the samples preclude any identification of a specific mantle source by its Li signature.  相似文献